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Der Substituent R⁶ befindet sich vorzugsweise in o- oder p-Position zur phenolischen OH-Gruppe, besonders in p-Position. R⁶ stellt beispielsweise Wasserstoff; C₁-C₁₂-Alkyl; C₆-C₁₈-Alkanoyl; Benzoyl; Methylbenzoyl; Dimethylbenzoyl; durch -Cl, -Br, -CN oder -OCH₃ substituiertes Benzoyl; α-Methylbenzyl; α,α-Dimethylbenzyl; N,N-Dialkylaminomethyl;. 1-Piperidylmethyl; 1-(4-Oxapiperidyl)methyl; ein Imid eines Acylrestes; oder α-(N-Alkylamino)alkyl dar. Vorzugsweise ist R⁶ Wasserstoff, C₁-C₆-Alkyl, Benzoyl, α-Methylbenzyl, Allyl oder ein Rest der Formeln. Alkylierte Monophenole, z.B.
2,6-Di-tert-butyl-4-methylphenol, 2-Butyl-4,6-dimethylphenol, 2,6-Di-tert-butyl-4-ethylphenol, 2,6-Di-tert-butyl-4-n-butylphenol, 2,6-Di-tert-butyl-4-iso-butylphenol, 2,6-Di-cyclopentyl-4-methylphenol, 2-(α-Methylcyclohexyl)-4,6-dimethylphenol, 2,6-Di-octadecyl-4-methylphenol, 2,4,6-Tri-cyclohexylphenol, 2,6-Di-tert-butyl-4-methoxymethylphenol, lineare oder in der Seitenkette verzweigte Nonylphenole wie z.B. 2,6-Di-nonyl-4-methylphenol, 2,4-Dimethyl-6-(1'-methyl-undec-1'-yl)-phenol, 2,4-Dimethyl-6-(1'-methyl-heptadec-1'-yl)-phenol, 2,4-Dimethyl-6-(1'-methyl-tridec-1'-yl)-phenol und Mischungen davon. Alkyliden-Bisphenole, z.B. Triazinverbindungen, z.B. Aminische Antioxidantien, wie z.B.
2-(2'-Hydroxyphenyl)-benzotriazole, wie z.B. 2-(2-Hydroxyphenyl)-1,3,5-triazine, wie z.B. Phosphite und Phosphonite, wie z.B. Benzofuranone bzw. Indolinone, wie z.B.
In US-A-4 325 863, US-A-4 338 244, US-A-5 175 312, US-A-5 216 052, US-A-5 252 643, DE-A-4 316 611, DE-A-4 316 622, DE-A-4 316 876, EP-A-0 589 839 oder EP-A-0 591 102 beschrieben, oder 3-4-(2-Acetoxyethoxy)phenyl-5,7-di-tert-butyl-benzofuran-2-on, 5,7-Di-tert-butyl-3-4-(2-stearoyloxyethoxy)phenyl-benzofuran-2-on, 3,3'-Bis5,7-di-tert-butyl-3-(4-2-hydroxyethoxy-phenyl)-benzofuran-2-on, 5,7-Di-tert-butyl-3-(4-ethoxyphenyl)benzofuran-2-on, 3-(4-Acetoxy-3,5-dimethylphenyl)-5,7-di-tert-butyl-benzofuran-2-on, 3-(3,5-Dimethyl-4-pivaloyloxy-phenyl)-5,7-di-tert-butyl-benzofuran-2-on. Vorzugsweise ist Q Halogen (z.B. Fluor, Chlor, Brom); Alkoxy (z.B. Ethoxy, Dodecyloxy, Methoxyethylcarbamoylmethoxy, Carboxypropyloxy, Methylsulfonylethoxy, Ethoxycarbonylmethoxy); Aryloxy (z.B. 4-Methylphenoxy, 4-Chlorphenoxy, 4-Methoxyphenoxy, 4-Carboxyphenoxy, 3-Ethoxycarboxyphenoxy, 3-Acetylaminophenoxy, 2-Carboxyphenoxy); Acyloxy (z.B.
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Acetoxy, Tetradecanoyloxy, Benzoyloxy); Alkyl- oder Aryl-sulfonyloxy (z.B. Methansulfonyloxy, Toluolsulfonyloxy); Acylamino (z.B. Dichloracetylamino, Heptafluorobutyrylamino); Alkyl- oder Arylsulfonamido (z.B. Methanesulfonamido, Trifluoromethansulfonamido, p-Toluolsulfonylamido); Alkoxycarbonyloxy (z.B. Ethoxycarbonyloxy, Benzyloxycarbonyloxy); Aryloxycarbonyloxy (z.B. Phenoxycarbonyloxy); Alkyl-, Aryl- oder Heterocyclyl-S- (z.B.
Dodecylthio, 1-Carboxydodecylthio, Phenylthio, 2-Butoxy-5-t-octylphenylthio, Tetrazolylthio); Carbamoylamino (z.B. N-Methylcarbamoylamino, N-Phenylcarbamoylamino); 5- oder 6-gliedriger stickstoffhaltiger Ring (z.B. Imidazolyl, Pyrazolyl, Triazolyl, Tetrazolyl, 1,2-Dihydro-2-oxo-1-pyridyl); Imido (z.B. Succinimido, Hydantoinyl); Arylazo (z.B.
Phenylazo, 4-Methoxyphenylazo). Weitere Beispiele von Cyankupplern sind in folgenden US-A- zu finden: 2,369,929, 2,423,730, 2,434,272, 2,474,293, 2,521,293, 2,521,908, 2,698,794, 2,706,684, 2,772,162, 2,801,171, 2,895,826, 2,908,573, 3,034,892, 3,046,129, 3,227,550, 3,253,294, 3,311,476, 3,386,301, 3,419,390, 3,458,315, 3,476,560, 3,476,563, 3,516,831, 3,560,212, 3,582,322, 3,583,971, 3,591,383, 3,619,196, 3,632,347, 3,652,286, 3,737,326, 3,758,308, 3,839,044, 3,880,661, 4,004,929, 4,124,396, 4,333,999, 4,463,086, 4,456,681, 4,873,183 und 4,923,791 und in den EP-A-354,549 und EP-A-398,664.
Phosphate: GB-A-791,219, BE-A-755,248, JP-A-76/76739, 78/27449, 78/218,252, 78/97573, 79/148,133, 82/216,177, 82/93323 und 83/216,177 und EP-A265,296. Phthalate: GB-A-791,219, JP-A-77/98050, 82/93322, 82/216,176, 82/218,251, 83/24321, 83/45699, 84/79888. Amide: GB-A-791,129, JP-A-76/105,043, 77/13600, 77/61089, 84/189,556, 87/239,149, US-A-928,741, EP-A-270,341, WO 88/00723. Phenole: GB-A-820,329, FR-A-1,220,657, JP-A-69/69946, 70/3818, 75/123,026, 75/82078, 78/17914, 78/21166, 82/212,114 und 83/45699.
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